There are several ways to spot the difference between the A and B version of the Mark IV.
The A have a straight lower edge to the front panel so the "Mark IV" logo beneath the standby switch is set lower, closer to the lower edge:
The B has a rounded low edge to the front panel, so the "Mark IV" logo is set closer to the Standby switch and the knobs are closer to the edge:
The A has two effects loops, a normal and a switchable. And the back will look like this:
The B has only one loop and the satellite send so the loop will look like this (this is a wide body combo. That´s why some of the switches are missing on the back. They are on the front instead):
Other things to look for: the A version uses a 12AT7 preamp tube for reverb. The B uses 12AX7.
The B version has a jack for reverb on/off switching on the back.
Soundwise, the B is a little darker and slightly smoother in the lead mode. It seems to have a little more gain (or at least more compression) to it aswell. Rhy 2 on the B has slightly more gain aswell. Rhy seems about the same.
But as others have said, the differences are very small. Only noticable when comparing them side by side. I´ve owned two different A´s and now I have a B. I couldn´t tell you which version I prefer. Both sound like the Mark IV and are great amps!