Jeez. This thread has really taken a turn. I almost want to hunt down a Mark IV just so I can figure out what people are talking about.
To get back on track however, I have honestly found that the Mark V 90, especially on the high gain channels, doesn't really respond to a lot of tube rolling. Maybe my speaker isn't broken in enough for it, but in general I found much more use putting different tubes in the lower gain channels, input drivers, and phase inverters than in any of the high gain stages. Looking at the schematics can help you determine what function a tube is doing, and if it's just a cold clipper, I'm not sure if you get much of a difference.