switching the main off may help to dissipate current trapped in the caps. I dont think it really matters how you turn your amp off, because it is not like turning them on at all.
The reason for the warm up is to excite electrons in the vacuum tube so that there is an adequate amound "flying" around the tube so that it doesnt damage any of the coatings or put a huge strain on the amp when you flip the standby off.
There is no such drain when you turn it off, the only thing might be attempting to drain the "flying" electrons from the tube, but by leaving the amp on stand by, with the heaters on, exciting electrons, this completely negates this act.
The only cool down method you should use, is to let your tubes cool down almost completely before moving your amp. Because of the high heat in the tube, and how fragile the components are, they become more fragile and flexible when they are hot, so moving or bumping them can increase the chances of shorting a tube or blowing the filament