OK, couple things.
First, you have one 16 ohm speaker and one 8 ohm speaker. On a Mark IV, you're going to want to hook each speaker up to each of the two "4 ohm" speaker out jacks. These are designed to hook up two 8 ohm speakers (or two 8 ohm cabs). Normally, you would un-plug the internal combo speaker (in your case, the EV), and re-plug it into one of the "4 ohm" jacks, and plug an 8 ohm extension cab into the other "4 ohm" jack. You would then leave the "8 ohm" jack empty. (Please don't be tempted to experiment with this empty speaker jack until you learn a bit more about speaker impedances and how to avoid blowing up your amp by going too low in speaker output impedance.)
Ahem.
Unfortunately, with two different speaker impedances (8 & 16 ohms), what happens is the lower impedance is going to get more power, because it has lower resistance.
To wit: One 8 ohm (A) and one 16 ohm (B) in parallel equals:
Amp output = 85 watts
Total Impedance = 5.33 Ω
Speaker A Power = 56.66 Watts (into 8 ohms)
Speaker B Power = 28.33 Watts (into 16 ohms)
The bit about "Total Impedance" is rather important. You don't want to go below 2 ohms total, so on this issue you would be OK, as you are between 8 ohms (ideal) and 4 ohms (a 100% mis-match, the maximum allowable).
You won't break anything doing this, so try it out and find out if the changes to the sound suit you. Report your findings here. We'll wait...
My two cents worth is, find a Thiele with a C90. Put the C90 in the combo, and the EV in the cab. Enjoy.